FOR IMMEDIATE RELEASE聽|聽August 12, 2014
Could hemp nanosheets topple graphene for making the ideal supercapacitor?
Note to journalists: Please report that this research will be presented at a meeting of the American Chemical 中国365bet中文官网.
SAN FRANCISCO, Aug. 12, 2014 鈥� As hemp makes a comeback in the U.S. after a decades-long ban on its cultivation, scientists are reporting that fibers from the plant can pack as much energy and power as graphene, long-touted as the model material for supercapacitors. They鈥檙e presenting their
research, which a Canadian start-up company is working on scaling up, at the 248th National Meeting & Exposition of the American Chemical 中国365bet中文官网 (ACS), the world鈥檚 largest scientific society.
The meeting features nearly 12,000 presentations on a wide range of science topics and is being held here through Thursday.
David Mitlin, Ph.D., explains that supercapacitors are energy storage devices that have huge potential to transform the way future electronics are powered. Unlike today鈥檚 rechargeable batteries, which sip up energy over several hours, supercapacitors can charge and discharge within seconds. But they normally can鈥檛 store nearly as much energy as batteries, an important property known as energy density. One approach researchers are taking to boost supercapacitors鈥� energy density is to design better electrodes. Mitlin鈥檚 team has figured out how to make them from certain hemp fibers 鈥� and they can hold as much energy as the current top contender: graphene.
鈥淥ur device鈥檚 electrochemical performance is on par with or better than graphene-based devices,鈥� Mitlin says. 鈥淭he key advantage is that our electrodes are made from biowaste using a simple process, and therefore, are much cheaper than graphene.鈥�
The race toward the ideal supercapacitor has largely focused on graphene 鈥� a strong, light material made of atom-thick layers of carbon, which when stacked, can be made into electrodes. Scientists are investigating how they can take advantage of graphene鈥檚 unique properties to build better solar cells, water filtration systems, touch-screen technology, as well as batteries and supercapacitors. The problem is it鈥檚 expensive.
Mitlin鈥檚 group decided to see if they could make graphene-like carbons from hemp bast fibers. The fibers come from the inner bark of the plant and often are discarded from Canada鈥檚 fast-growing industries that use hemp for clothing, construction materials and other products. The U.S. could soon become another supplier of bast. It now allows limited cultivation of hemp, which unlike its close cousin, does not induce highs.
Scientists had long suspected there was more value to the hemp bast 鈥� it was just a matter of finding the right way to process the material.
鈥淲e鈥檝e pretty much figured out the secret sauce of it,鈥� says Mitlin, who鈥檚 now with Clarkson University in New York. 鈥淭he trick is to really understand the structure of a starter material and to tune how it鈥檚 processed to give you what would rightfully be called amazing properties.鈥�
His team found that if they heated the fibers for 24 hours at a little over 350 degrees Fahrenheit, and then blasted the resulting material with more intense heat, it would exfoliate into carbon nanosheets.
Mitlin鈥檚 team built their supercapacitors using the hemp-derived carbons as electrodes and an ionic liquid as the electrolyte. Fully assembled, the devices performed far better than commercial supercapacitors in both energy density and the range of temperatures over which they can work. The hemp-based devices yielded energy densities as high as 12 Watt-hours per kilogram, two to three times higher than commercial counterparts. They also operate over an impressive temperature range, from freezing to more than 200 degrees Fahrenheit.
鈥淲e鈥檙e past the proof-of-principle stage for the fully functional supercapacitor,鈥� he says. 鈥淣ow we鈥檙e gearing up for small-scale manufacturing.鈥�
Mitlin, who conducted the research while at the University of Alberta, acknowledges funding from , (Canada) and .
The American Chemical 中国365bet中文官网 is a nonprofit organization chartered by the U.S. Congress. With more than 161,000 members, ACS is the world鈥檚 largest scientific society and a global leader in providing access to chemistry-related research through its multiple databases, peer-reviewed journals and scientific conferences. Its main offices are in Washington, D.C., and Columbus, Ohio.
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